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Bridgmanite

MgSiO3

third-order Birch-Murnaghan · Original · 1993

Why this differs from similar rows?

Ab initio calculation for a hypothetical cubic phase (K0=258, K'0=4.0); sibling row is for the Pbnm (orthorhombic) phase of the same composition (K0=259, K'0=3.9).

V₀
Unknown basis
K₀
258
GPa
Unknown
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
Unknown basis

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1
SiO21

Formula: MgSiO3

Conditions & method

Tref
Pref
Structure
cubic perovskite (Pm-3m)
Method
molecular dynamics
ab initio (LDA pseudopotential plane-wave) constant-pressure molecular dynamics / structural optimization, static (zero temperature)
Sample
ab initio calculated hypothetical cubic phase

Source

Paper
Ab initiomolecular dynamics with variable cell shape: Application toMgSiO3
Authors
Renata M. Wentzcovitch; José Luı́s Martins; G. D. Price
DOI
10.1103/physrevlett.70.3947
Year
1993
Journal
Physical Review Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

These and their pressure derivatives are K0 = 259 and 258 GPa and K'0 = 3.9 and 4.0 for the Pbnm and cubic phases, respectively.

Additional notes

zero pressure lattice parameter calc Angstrom
3.472
note
The calculated zero pressure lattice parameter of the Pm3m is 3.472 Å (in contrast to 3.48 [28]).