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Bridgmanite

MgSiO3 with 5 mol% Al2O3

third-order Birch-Murnaghan · Original · 1999

Why this differs from similar rows?

Table 3, Run 1 of the in situ P-V-T XRD experiment; ambient V0 fixed to the measured Run 1 unit-cell volume (163.051 A3), distinct from Runs 2 and 3.

V₀
163.051
ų
Unit cell
K₀
234
GPa
Isothermal
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
163.051 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1
SiO21

Formula: MgSiO3

Conditions & method

Tref
300 K
Pref
Structure
orthorhombic perovskite (Pbnm/Pnma)
Method
experiment (XRD / DAC / multianvil compression)
in situ P-V-T X-ray diffraction (multi-anvil press, NaCl medium)
Sample
Al-Pv, Run 1

Source

Paper
Thermal Equation of State of Aluminum-Enriched Silicate Perovskite
Authors
Jianzhong Zhang; Donald J. Weidner
DOI
10.1126/science.284.5415.782
Year
1999
Journal
Science
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 3: Al-Pv, Run 1: K_{0,T} = 234(2) GPa; 'In all studies, the pressure derivative, K_0', is fixed at 4. Ambient unit-cell volume, V_0, was fixed in the data reduction of this study.' Table 1, Run 1 (beginning of run): V = 163.051(69) ų.

Additional notes

dKT dT GPa per K HT BM
-0.055(10)
dKT dT GPa per K isothermal PV
-0.057(5)
alpha0 x1e5
2.08(26)
alpha1 x1e8
2.21(67)
beta a x1e3 GPa-1
1.42(2)
beta b x1e3 GPa-1
1.24(1)
beta c x1e3 GPa-1
1.37(2)
V0 note
Table 1 also lists end-of-run volume 163.126(61) ų for Run 1; V0 was fixed to measured ambient value in the fit