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Ferropericlase

(Mg0.96875Fe0.03125)O

third-order Birch-Murnaghan · Original · 2020

V₀
73.66
ų
Unit cell
K₀
172.100
GPa
Unknown
K′
4.150
dimensionless

Volume (V₀)

Value Unit Basis Z
73.66 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO0.96875
FeO0.03125

Formula: (Mg0.96875Fe0.03125)O

Conditions & method

Tref
Pref
Structure
B1 rocksalt (Fm-3m)
Method
DFT+U / DFT+DMFT
static ab initio DFT LSDA+Usc calculation
Sample
3Fp, LS state, 64-atom supercell with one Fe

Source

Paper
Phonon dispersion throughout the iron spin crossover in ferropericlase
Authors
Michel L. Marcondes; Fawei Zheng; Renata M. Wentzcovitch
DOI
10.1103/physrevb.102.104112
Year
2020
Journal
Physical review. B./Physical review. B
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

TABLE I. Equation of state parameters obtained in static LSDA +Usc calculations in Fp. XFe 0.031 25, LS: V0 (Å3) 73.66, K0 (GPa) 172.1, K0' 4.15. 'The energy vs volume curve was fitted to a third-order finite strain equation of state [31].'

Additional notes

conditions
static (0 K) calculation
spin state
low spin (LS)