Periclase
MgO
Birch-Murnaghan (order unspecified) · Original · 1990
V₀
—
Unknown basis
K₀
162
GPa
Isothermal
K′
—
dimensionless
Volume (V₀)
| Value | Unit | Basis | Z |
|---|---|---|---|
| — | — | Unknown basis | — |
Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.
Composition
| Oxide | Molar |
|---|---|
| MgO | 1 |
Formula: MgO
Conditions & method
- Tref
- 300 K
- Pref
- —
- Structure
- B1 rocksalt (Fm-3m)
- Method
- experiment (Brillouin / ultrasonic / elasticity)calculated from measured adiabatic bulk modulus (resonance elasticity measurements) via K_S/K_T = 1 + αγT
- Sample
- MgO, zero-pressure reference state (P = 0, T = 300 K)
Source
- Paper
- Thermodynamic Functions and Properties of MgO at High Compression and High Temp…
- Authors
- Orson L. Anderson; Keshan Zou
- DOI
- 10.1063/1.555873
- Year
- 1990
- Journal
- Journal of Physical and Chemical Reference Data
- Origin
- Original (measured or fitted in the source paper)
Evidence from the paper
Table 2. Thermodynamic data calculated from Table 1: T = 300 K, K_T = 162 GPa. 'The Birch Murnaghan equation of state is used ... The parameters used in the Birch-Murnaghan equation of state are given as functions of temperature.' 'The reference volume V0 is taken at P = 0 and T = 300 K.'
Additional notes
rho0 300K
3.585 g/ml (Table 1); text also quotes rho0 = 3.587 g/ml in a worked example
alpha 300K
31.2 x 10^-6 K^-1
gamma 300K
1.54
note
K_T derived from K_S using 1 + alpha*gamma*T correction; K' not reported in the provided excerpt; V0 given only as reference density, not as unit-cell or molar volume