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Periclase

MgO

Birch-Murnaghan (order unspecified) · Original · 1990

V₀
Unknown basis
K₀
162
GPa
Isothermal
K′
dimensionless

Volume (V₀)

Value Unit Basis Z
Unknown basis

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1

Formula: MgO

Conditions & method

Tref
300 K
Pref
Structure
B1 rocksalt (Fm-3m)
Method
experiment (Brillouin / ultrasonic / elasticity)
calculated from measured adiabatic bulk modulus (resonance elasticity measurements) via K_S/K_T = 1 + αγT
Sample
MgO, zero-pressure reference state (P = 0, T = 300 K)

Source

Paper
Thermodynamic Functions and Properties of MgO at High Compression and High Temp…
Authors
Orson L. Anderson; Keshan Zou
DOI
10.1063/1.555873
Year
1990
Journal
Journal of Physical and Chemical Reference Data
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 2. Thermodynamic data calculated from Table 1: T = 300 K, K_T = 162 GPa. 'The Birch Murnaghan equation of state is used ... The parameters used in the Birch-Murnaghan equation of state are given as functions of temperature.' 'The reference volume V0 is taken at P = 0 and T = 300 K.'

Additional notes

rho0 300K
3.585 g/ml (Table 1); text also quotes rho0 = 3.587 g/ml in a worked example
alpha 300K
31.2 x 10^-6 K^-1
gamma 300K
1.54
note
K_T derived from K_S using 1 + alpha*gamma*T correction; K' not reported in the provided excerpt; V0 given only as reference density, not as unit-cell or molar volume