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CaSiO3

Birch-Murnaghan (order unspecified) · Cited · 1996

Why this differs from similar rows?

Refit of Mao et al. [1989] DAC data (to 134 GPa, no pressure medium) with K0' fixed to 4.0; a different original dataset from the Wang et al. [1996] refit in sibling row 530.

V₀
45.37
ų
Unit cell
K₀
281
GPa
Isothermal
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
45.37 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
CaO1
SiO21

Formula: CaSiO3

Conditions & method

Tref
300 K
Pref
Structure
cubic perovskite (Pm-3m)
Method
experiment (XRD / DAC / multianvil compression)
room temperature x-ray diffraction in diamond anvil cell without a pressure medium, to 134 GPa (non-hydrostatic, laser-heated to minimize gradients)
Sample
Experiment: Mao et al. (1989), constrained fit K0'=4, Table 2

Source

Paper
First‐principles calculation of the equation‐of‐state, stability, and polar opt…
Authors
A. V. G. Chizmeshya; George H. Wolf; Paul F. McMillan
DOI
10.1029/96gl02624
Year
1996
Journal
Geophysical Research Letters
Origin
Cited (quoted from earlier work)

Evidence from the paper

'A weighted least-squares fit of these data to a Birch-Murnaghan equation of state yields values of V0 = 45.37(8) Å3 and K0 = 281(4) GPa for the volume and isothermal bulk modulus of CaSiO3 perovskite at ambient pressure (obtained by fixing the pressure derivative of the bulk modulus, K0', to 4.0).' Table 2: Mao et al (1989)*: V0 = 45.37 Å3, K0 = 281 GPa, K0' = 4.00.

Additional notes

reference
Mao et al. [1989]
pressure range
to 134 GPa