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CaSiO3

Birch-Murnaghan (order unspecified) · Cited · 1996

Why this differs from similar rows?

Refit of Wang et al. [1996] (WWG) XRD data with K0' fixed to 4.0; a different original dataset from the Mao et al. [1989] refit in sibling row 531.

V₀
45.59
ų
Unit cell
K₀
233
GPa
Isothermal
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
45.59 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
CaO1
SiO21

Formula: CaSiO3

Conditions & method

Tref
300 K
Pref
Structure
cubic perovskite (Pm-3m)
Method
experiment (XRD / DAC / multianvil compression)
x-ray diffraction, cubic anvil device with NaCl pressure medium and external heating, up to 13 GPa and 1600 K (quasi-hydrostatic)
Sample
Experiment: WWG (1996) / Wang et al. [1996] refined data set, constrained fit K0'=4, Table 2

Source

Paper
First‐principles calculation of the equation‐of‐state, stability, and polar opt…
Authors
A. V. G. Chizmeshya; George H. Wolf; Paul F. McMillan
DOI
10.1029/96gl02624
Year
1996
Journal
Geophysical Research Letters
Origin
Cited (quoted from earlier work)

Evidence from the paper

'Using their refined data set and fixing K0' to 4.0, values of V0 = 45.59(4) Å3 and K0 = 233(7) GPa for the equation of state parameters are obtained.' Table 2: Experiment WWG (1996)*: V0 = 45.59 Å3, K0 = 233 GPa, K0' = 4.00.

Additional notes

data source
Wang et al. [1996]
note
fit to Wang et al. data with excessive non-hydrostatic/amorphized low-pressure points excluded