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CaSiO3

Birch-Murnaghan (order unspecified) · Cited · 1996

Why this differs from similar rows?

PHF (Sherman, 1993) thermally-corrected fit with K0' fixed to 4 (constrained fit, denoted by asterisk); sibling row uses the same PHF data but fits K0' freely (4.45).

V₀
45.43
ų
Unit cell
K₀
290.500
GPa
Isothermal
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
45.43 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
CaO1
SiO21

Formula: CaSiO3

Conditions & method

Tref
300 K
Pref
Structure
cubic perovskite (Pm-3m)
Method
unknown
periodic Hartree-Fock (PHF) with 300 K thermal correction
Sample
PHF* thermally corrected (300 K), constrained fit K0'=4 (Sherman, 1993), Table 2

Source

Paper
First‐principles calculation of the equation‐of‐state, stability, and polar opt…
Authors
A. V. G. Chizmeshya; George H. Wolf; Paul F. McMillan
DOI
10.1029/96gl02624
Year
1996
Journal
Geophysical Research Letters
Origin
Cited (quoted from earlier work)

Evidence from the paper

Table 2: PHF a* (Sherman, 1993. Non-relativistic total energy; constrained EoS fit with K0' = 4): E0 = -1190.67640 Hartree, V0 = 45.43 Å3, K0 = 290.5 GPa, K0' = 4.00.

Additional notes

E0 Hartree
-1190.6764
reference
Sherman [1993]
note
thermal correction applied as in the LAPW calculation of the present study