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CaSiO3

Birch-Murnaghan (order unspecified) · Original · 1996

Why this differs from similar rows?

New in situ synchrotron XRD (SAM-85 cubic-anvil) measurement (Table 4), a different dataset from the Mao et al. [1989] DAC-data refits reported in sibling rows.

V₀
27.45
cm³/mol
Molar
K₀
232
GPa
Isothermal
K′
4.800
dimensionless

Volume (V₀)

Value Unit Basis Z
27.45 cm³/mol Molar

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
CaO1
SiO21

Formula: CaSiO3

Conditions & method

Tref
Pref
Structure
cubic perovskite (Pm-3m)
Method
experiment (XRD / DAC / multianvil compression)
in situ synchrotron X-ray diffraction, DIA-6 cubic-anvil apparatus (SAM-85)
Sample
Table 4 thermoelastic parameters (molar basis, used for lower mantle extrapolation)

Source

Paper
Thermal equation of state of CaSiO3 perovskite
Authors
Yanbin Wang; Donald J. Weidner; François Guyot
DOI
10.1029/95jb03254
Year
1996
Journal
Journal of Geophysical Research Atmospheres
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 4 'Thermoelastic Parameters for MgSiO3 and CaSiO3 Perovskites', CaSiO3 column: V0 = 27.45 cm^3 mol^-1, rho0 = 4.231 g cm^-3, K_T0 = 232 GPa, K'_T0 = 4.8, (dKT/dT)_P = -0.033 GPa/K.

Additional notes

rho0
4.231 g cm^-3
alpha0
3.01 x 10^-5 K^-1
theta0
1100 K (from Wang and Weidner [1994])
delta T0
4.8
gamma0
1.77
q
1 (assumed pressure dependence of Grüneisen parameter through volume)