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CaSiO3

third-order Birch-Murnaghan · Original · 1996

V₀
45.58
ų
Unit cell
K₀
232
GPa
Isothermal
K′
4.800
dimensionless

Volume (V₀)

Value Unit Basis Z
45.58 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
CaO1
SiO21

Formula: CaSiO3

Conditions & method

Tref
Pref
Structure
cubic perovskite (Pm-3m)
Method
experiment (XRD / DAC / multianvil compression)
in situ synchrotron X-ray diffraction, DIA-6 cubic-anvil apparatus (SAM-85), NaCl pressure medium
Sample
synthesized in situ from synthetic wollastonite

Source

Paper
Thermal equation of state of CaSiO3 perovskite
Authors
Yanbin Wang; Donald J. Weidner; François Guyot
DOI
10.1029/95jb03254
Year
1996
Journal
Journal of Geophysical Research Atmospheres
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

"We thus adopt K'_T0 = 4.8 from the above analysis on Mao et al. data in fitting our data with equation (1) to obtain K_T0 = 232(8) GPa and V0 = 45.58(4) Å^3 for our data"; abstract: "K_T0 = 232(8) GPa, K'_T0 = 4.8(3), and V0 = 45.58(4) Å^3".

Additional notes

note
Preferred parameter set of this study; K'_T0 = 4.8 adopted (fixed) from the authors' fit to Mao et al. [1989] data where its uncertainty is 4.8(3). With fixed K'_T0 from 3 to 5, K_T0 ranges 238(7) to 227(7) GPa and V0 ranges 45.58(4) to 45.60(4) Å^3.
dKT dT P
-0.033(8) GPa K^-1
alpha0
3.0 x 10^-5 K^-1
delta T
4.8