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Bridgmanite

MgSiO3

third-order Birch-Murnaghan · Original · 1994

Why this differs from similar rows?

Lattice-dynamics (LD) quasi-harmonic simulation result at 1000 K/0 GPa; sibling row uses a molecular-dynamics (MD) simulation instead, giving K_T=208 GPa versus 200 GPa here.

V₀
25.25
cm³/mol
Molar
K₀
200
GPa
Isothermal
K′
dimensionless

Volume (V₀)

Value Unit Basis Z
25.25 cm³/mol Molar

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1
SiO21

Formula: MgSiO3

Conditions & method

Tref
1000 K
Pref
Structure
orthorhombic perovskite (Pbnm/Pnma)
Method
first-principles DFT / ab initio
lattice dynamics (LD) simulation (quasi-harmonic approximation, PARAPOCS code, IMAMOK pair potential)
Sample
Table 2, LD simulation, 1000 K / 0 GPa

Source

Paper
Comparison between the lattice dynamics and molecular dynamics methods: Calcula…
Authors
Masanori Matsui; G. D. Price; A. B. Patel
DOI
10.1029/94gl01370
Year
1994
Journal
Geophysical Research Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 2: T/K 1000, P/GPa 0, V/(cm3/mol) LD 25.25, K_T/GPa LD 200(2). K_T's obtained by fitting simulated P-V relations to a third-order Birch-Murnaghan equation.

Additional notes

alpha 10^-5 K^-1
5.32(9)
note
Volume and bulk modulus are simulation-derived, not experimental; K_T from BM3 fit to simulated P-V relations; no K' value reported.