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Superhydrous phase B

Mg8.93Si2.72Al0.56O18H5.57

finite strain (unspecified form) · Original · 2024

Why this differs from similar rows?

Global high-P-T fit over 11.4-23.5 GPa/300-900 K including a dK/dT term; sibling row is the room-temperature-only fit (11.4-21.1 GPa/300 K).

V₀
621.41
ų
Unit cell
K₀
147
GPa
Adiabatic
K′
4.400
dimensionless

Volume (V₀)

Value Unit Basis Z
621.41 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO8.93
Al2O30.28
SiO22.72
H2O2.785

Formula: Mg8.93Si2.72Al0.56O18H5.57

Conditions & method

Tref
300 K
Pref
Structure
other / unspecified
Method
experiment (Brillouin / ultrasonic / elasticity)
ultrasonic interferometry (VP, VS) + synchrotron X-ray diffraction density in Kawai-type multi-anvil apparatus
Sample
S3358 (polycrystalline), high P-T global fit

Source

Paper
Effect of Al‐Incorporation on the Sound Velocities of Superhydrous Phase B at H…
Authors
Chaowen Xu; Steeve Gréaux; Ying Chun Li; Fengxia Sun; Jing Gao; Fei Qin; Toru Inoue
DOI
10.1029/2023gl107818
Year
2024
Journal
Geophysical Research Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 1 (Finite strain EoS, P-scale free): S3358, 11.4–23.5 GPa/300–900 K, V0 = 621.41a, 147 (2), 4.4 (1), ∂KS/∂T = −0.017 (1), G0 = 93.9 (9), ∂G/∂P = 1.8 (3), ∂G/∂T = −0.019 (1), α0 = 4.3a.

Additional notes

dKS dT GPa per K
−0.017 (1)
G0 GPa
93.9 (9)
dG dP
1.8 (3)
dG dT GPa per K
−0.019 (1)
alpha0 1e-5 per K
4.3 (fixed)
P T conditions
11.4–23.5 GPa / 300–900 K
V0 fixed in fit
True