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Superhydrous phase B

Mg8.99Si2.77Al0.54O18H5.25

third-order Birch-Murnaghan · Original · 2024

V₀
621.69
ų
Unit cell
K₀
137
GPa
Isothermal
K′
4.430
dimensionless

Volume (V₀)

Value Unit Basis Z
621.69 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO8.99
Al2O30.27
SiO22.77
H2O2.625

Formula: Mg8.99Si2.77Al0.54O18H5.25

Conditions & method

Tref
300 K
Pref
Structure
other / unspecified
Method
experiment (Brillouin / ultrasonic / elasticity)
synchrotron energy-dispersive X-ray diffraction + ultrasonic interferometry in Kawai-type multi-anvil apparatus
Sample
S3359 (polycrystalline)

Source

Paper
Effect of Al‐Incorporation on the Sound Velocities of Superhydrous Phase B at H…
Authors
Chaowen Xu; Steeve Gréaux; Ying Chun Li; Fengxia Sun; Jing Gao; Fei Qin; Toru Inoue
DOI
10.1029/2023gl107818
Year
2024
Journal
Geophysical Research Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Text: 'K_T0 = 136.6 (2) GPa and K'_T0 = 4.43 (fixed) for S3359'. Table 1: S3359, 14.8–21.2 GPa/300 K, V0 = 621.69a, 137 (2), 4.43a, −0.018a, α0 4.6 (2). Ambient XRD: V = 621.69(17) Å3 for S3359.

Additional notes

note
Text quotes K_T0 = 136.6 (2) GPa while Table 1 lists 137 (2) GPa
dKT dT GPa per K
−0.018 (fixed)
alpha0 1e-5 per K
4.6 (2)
P T conditions
14.8–21.2 GPa / 300 K
V0 fixed in fit
True
pressure scale
gold (Tsuchiya, 2003)