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Phase D

20.7 wt% MgO, 44.5 wt% SiO2, 18.8 wt% Al2O3, ~16.0 wt% H2O (EDS)

Birch-Murnaghan (order unspecified) · Original · 2020

Why this differs from similar rows?

Table 1 row where K (=143) is fixed alongside V0 ('the value was fixed when calculated') and only K' (5.85) and thermal terms are fitted; sibling row instead lets K float (=142, K'=6.0).

V₀
86.71
ų
Unit cell
K₀
143
GPa
Isothermal
K′
5.850
dimensionless

Volume (V₀)

Value Unit Basis Z
86.71 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO0.8968
Al2O30.322
SiO21.2932
H2O1.5508

Formula: 20.7 wt% MgO, 44.5 wt% SiO2, 18.8 wt% Al2O3, ~16.0 wt% H2O (EDS)

Conditions & method

Tref
300 K
Pref
Structure
other / unspecified
Method
experiment (Brillouin / ultrasonic / elasticity)
in situ synchrotron X-ray diffraction with ultrasonic measurements in Kawai-type multianvil apparatus (Gold P-scale, Tsuchiya, 2003)
Sample
Al-PhD, Table 1, Birch-Murnaghan EoS, 0-23 GPa/300-900 K (row with K0 fixed)

Source

Paper
Sound Velocities of Al‐Bearing Phase D up to 22 GPa and 1300 K
Authors
Chaowen Xu; Steeve Gréaux; Toru Inoue; Masamichi Noda; Wei Sun; H. Kuwahara; Yuji Higo
DOI
10.1029/2020gl088877
Year
2020
Journal
Geophysical Research Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 1: Al-PhD, 0-23 GPa/300-900 K, V0 = 86.71a, K = 143a, K' = 5.85 (4), ∂K/∂T = -0.023(6), a = 3.5 (3) × 10^-5 K^-1, b = 0.9 (5) × 10^-8 K^-2. 'aThe value was fixed when calculated.'

Additional notes

P T range
0-23 GPa/300-900 K
dK dT
-0.023(6) GPa K^-1
a
3.5 (3) × 10^-5 K^-1
b
0.9 (5) × 10^-8 K^-2
V0 fixed
True
K0 fixed
True