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Post-perovskite

FeSiO3

third-order Birch-Murnaghan · Original · 2005

Why this differs from similar rows?

GGA value (Perdew et al. 1996) for ferromagnetic (FM) FeSiO3 post-perovskite; the LDA value for the same structure (V0=44.38, K0=212, K'=4.28) is given in the sibling row.

V₀
41.17
ų/f.u.
Formula unit
K₀
244
GPa
Isothermal
K′
4.250
dimensionless

Volume (V₀)

Value Unit Basis Z
41.17 ų/f.u. Formula unit

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
FeO1
SiO21

Formula: FeSiO3

Conditions & method

Tref
Pref
Structure
post-perovskite (CaIrO3-type, Cmcm)
Method
first-principles DFT / ab initio
first-principles static spin-polarized calculation (DFT-GGA)
Sample
ppv-FM (ferromagnetic)

Source

Paper
Effect of chemistry on the stability and elasticity of the perovskite and post‐…
Authors
Razvan Caracas; R. E. Cohen
DOI
10.1029/2005gl023164
Year
2005
Journal
Geophysical Research Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 1, FeSiO3 ppv-FM: V0 = 44.38(41.17) Å^3/3 O atoms, K0 = 212(244) GPa, K' = 4.28(4.25); GGA values in parentheses.

Additional notes

exchange correlation
GGA (Perdew et al., 1996)
magnetic state
ferromagnetic (FM)