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CaSiO3

Birch-Murnaghan (order unspecified) · Original · 2002

V₀
45.58
ų
Unit cell
K₀
255
GPa
Isothermal
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
45.58 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
CaO1
SiO21

Formula: CaSiO3

Conditions & method

Tref
Pref
Structure
other / unspecified
Method
experiment (XRD / DAC / multianvil compression)
high-resolution angle-dispersive synchrotron X-ray diffraction in laser-heated diamond anvil cell, 20-46 GPa
Sample
Ca-pv synthesized from natural wollastonite in laser-heated diamond anvil cell, Pt pressure standard, Ar medium

Source

Paper
Tetragonal structure of CaSiO3 perovskite above 20 GPa
Authors
Sang‐Heon Shim; Raymond Jeanloz; T. S. Duffy
DOI
10.1029/2002gl016148
Year
2002
Journal
Geophysical Research Letters
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Fitting our data points to the Birch-Murnaghan equation assuming that the pressure derivative of the isothermal bulk modulus is 4 and the volume at ambient conditions is 45.58 Å3 [Wang et al., 1996], the isothermal bulk modulus of Ca-pv is 255 ± 5 GPa; The bulk modulus of the tetragonal phase is 255 ± 5 GPa for K0T' = 4.

Additional notes

V0 source
Wang et al., 1996
pressure range of data
19.7-45.8 GPa
note
V0 taken from literature and held fixed in the fit; all previous measurements were analyzed based on a cubic unit cell whereas this study uses a tetragonal cell