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Ferropericlase

(Mg0.423Fe0.541□0.036)O (Fe56)

third-order Birch-Murnaghan · Original · 2002

V₀
77.453
ų
Unit cell
K₀
155.800
GPa
Isothermal
K′
5.530
dimensionless

Volume (V₀)

Value Unit Basis Z
77.453 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO0.423
FeO0.541

Formula: (Mg0.423Fe0.541□0.036)O

Conditions & method

Tref
Pref
0.000 GPa
Structure
B1 rocksalt (Fm-3m)
Method
experiment (XRD / DAC / multianvil compression)
single-crystal X-ray diffraction in diamond anvil cell (quartz internal pressure standard), static compression to 8.9 GPa
Sample
Fe56 single crystal, ΣFe/(ΣFe+Mg) = 0.561(2), Fe3+/ΣFe = 0.13(2)

Source

Paper
Structure and elasticity of single‐crystal (Mg,Fe)O and a new method of generat…
Authors
Steven D. Jacobsen; Hans‐J. Reichmann; H. Spetzler; S. J. Mackwell; Joseph R. Smyth; R. J. Angel; Catherine McCammon
DOI
10.1029/2001jb000490
Year
2002
Journal
Journal of Geophysical Research Atmospheres
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

For sample Fe56 (Mg0.423Fe0.541□0.036O) we obtain V0 = 77.453(4) Å3, K0T = 155.8(9) GPa, and K' = 5.53(23).

Additional notes

experimental zero pressure volume
77.453(5) Å3 (measured in DAC without pressure fluid)
max pressure
8.9 GPa (11 P-V data, Table 4)
ambient cell parameter Table1
a = 4.2621(2) Å