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Bridgmanite

MgSiO3

third-order Birch-Murnaghan · Original · 2013

V₀
162.378
ų
Unit cell
K₀
244
GPa
Isothermal
K′
4
dimensionless

Volume (V₀)

Value Unit Basis Z
162.378 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1
SiO21

Formula: MgSiO3

Conditions & method

Tref
Pref
Structure
orthorhombic perovskite (Pbnm/Pnma)
Method
first-principles DFT / ab initio
first-principles DFT (CASTEP, plane-wave norm-conserving pseudopotentials, GGA-PW91), static P-V fit
Sample
Table 1, first-principles calculated cell at 0 K, 0 GPa

Source

Paper
Effect of substitution Fe2+ on physical properties of MgSiO3 perovskite at high…
Authors
Di Wu; Zhao Ji-jun; Tian Hua
DOI
10.7498/aps.62.049101
Year
2013
Journal
Acta Physica Sinica
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

表 1 理论计算得到的斜方晶系 Pbnm 空间群的 MgSiO3 ... 晶胞体积/Å^3 162.378 ... B0/GPa 244 ... B'0 4.0; 结合三阶 Birch-Murnaghan 物态方程, 我们分别计算了 0 K 下 MgSiO3 和 (Mg0.75, Fe0.25)SiO3 晶胞的体积模量 B0 和 0 GPa 下体积模量对压力的一阶导数 B'

Additional notes

lattice parameters
a=4.7859 Å, b=4.9180 Å, c=6.8989 Å
note
V0 is the DFT-optimized zero-pressure, zero-temperature unit-cell volume from Table 1 used with the 3rd-order BM EOS fit