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Bridgmanite

MgSiO3

unknown · Original · 1993

V₀
24.56
cm³/mol
Molar
K₀
250
GPa
Unknown
K′
dimensionless

Volume (V₀)

Value Unit Basis Z
24.56 cm³/mol Molar

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1
SiO21

Formula: MgSiO3

Conditions & method

Tref
Pref
Structure
orthorhombic perovskite (Pbnm/Pnma)
Method
molecular dynamics
molecular dynamics simulation (constant-pressure Parrinello-Rahman / constant-temperature Nose MD with pair-potential model)
Sample
Table 2 (第2表), 'MD' row for perovskite

Source

Paper
Computer Simulation of the Structural and Physical Properties of Minerals in th…
Authors
Masanori Matsui
DOI
10.5940/jcrsj.35.190
Year
1993
Journal
Nihon Kessho Gakkaishi
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

第2表 MgSiO3多形の構造および物性の実測値とMD値の比較(P=0GPa): perovskite (Pbnm) — V/(cm3 mol-1) MD 24.56; K0/GPa MD 250. Footnote b: MD計算值16). Text: 体積弾性率についても高精度で実測値を再現…ペロフスカイトについて…1%であった(第2表).

Additional notes

alpha MD
2.9 x10-5 K-1 (volume thermal expansivity, MD)
enthalpy MD
-7150.0 kJ mol-1
determination note
Values are MD-calculated (computed from simulation), not experimentally measured or fitted to an analytic EOS; no enum matches computed, so 'unknown' used.
deviation from obs
MD bulk modulus differs from observed by 1% for perovskite