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Bridgmanite

(Fe0.08Mg0.92)SiO3

third-order Birch-Murnaghan · Original · 2011

Why this differs from similar rows?

Fit restricted to the P<70 GPa subset of run M868's data; sibling row uses the full dataset to >90 GPa. Deviation above 70 GPa is noted as possibly linked to an Fe spin transition.

V₀
Unknown basis
K₀
257
GPa
Isothermal
K′
4.300
dimensionless

Volume (V₀)

Value Unit Basis Z
Unknown basis

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO0.92
FeO0.08
SiO21

Formula: (Mg0.92Fe0.08)SiO3

Conditions & method

Tref
300 K
Pref
Structure
orthorhombic perovskite (Pbnm/Pnma)
Method
experiment (XRD / DAC / multianvil compression)
in situ X-ray diffraction in Kawai-type multianvil apparatus with sintered diamond anvils (SPring-8, SPEED-Mk.II)
Sample
sintered mixture of (Fe0.08Mg0.92)SiO3 perovskite and Au, run M868 (data restricted to P < 70 GPa)

Source

Paper
High Pressure Generation in a Kawai-Type Apparatus Equipped with Sintered Diamo…
Authors
Daisuke Yamazaki
DOI
10.4131/jshpreview.21.272
Year
2011
Journal
The Review of High Pressure Science and Technology
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

本実験から得られた体積データを 70 GPa 未満の領域と,70 GPa 以上の領域に分け,70 GPa 未満のデータを用いて,体積弾性率とその圧力微分値をもとめた(Fig. 8)。その結果,KT0=257 GPa,K′=4.3 となった。 (Fig. 8: The data in the pressure range less than 70 GPa were fitted to the third-order Birch-Murnaghan equation of state. The results show KT0 equal to 257 GPa and K′ equal to 4.3.)

Additional notes

pressure range
P < 70 GPa subset
note
Fit consistent with Katsura et al. [13]; deviation above 70 GPa possibly related to Fe spin transition in perovskite