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Periclase

MgO

Vinet · Original · 2025

V₀
74.71
ų
Unit cell
K₀
160.300
GPa
Isothermal
K′
5.230
dimensionless

Volume (V₀)

Value Unit Basis Z
74.71 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO1

Formula: MgO

Conditions & method

Tref
300 K
Pref
Structure
B1 rocksalt (Fm-3m)
Method
experiment (shock wave)
optimization combining static DAC compression, shock experiments, high-T XRD, elasticity (KS), and heat capacity (CP) datasets
Sample
MgO pressure standard (Table 1, this study's optimized P-V-T EOS)

Source

Paper
Internally consistent pressure-volume-temperature equations of state among plat…
Authors
Xi Zhu; Yu Ye; Wei Sun; Tomoo Katsura; Razvan Caracas
DOI
10.22541/essoar.176236186.65259830/v1
Year
2025
Journal
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 1. P-V-T EOS parameters optimized for Pt, Au, and MgO. | MgO: V0 (Å3) 74.71#; KT0 (GPa) 160.3#; KT0' 4.182(19)#; θ0 (K) 761*; γ0 1.52(4); a 1; b 1.5(1); β0 (10-5 J/g·K2) -2.0(1); m 4.8(1). #: Ye et al. (2017); *: Tange et al. (2009). 'In this study, the P-V Vinet (Vinet et al., 1986) EOSs (Eqn. 1) are adopted for Pt, Au, and MgO at the ambient temperature as in Ye et al. (2017)'

Additional notes

Kp verbatim
4.182(19)
static 300K parameters source
V0, KT0, KT0' adopted from Ye et al. (2017) inter-calibrated P-V Vinet EOSs at 300 K (marked # in Table 1)
theta0 K
761 (from Tange et al., 2009)
gamma0
1.52(4)
a
1
b
1.5(1)
beta0 1e-5 J per gK2
-2.0(1)
m
4.8(1)
note
Thermal (γ0, a, b, β0, m) parameters were optimized in this study; excess (anharmonic) contribution is negative for MgO