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Bridgmanite

(Mg0.88Fe3+0.065Fe2+0.035Al0.03)(Al0.11Si0.90)O3

Birch-Murnaghan (order unspecified) · Original · 2023

Why this differs from similar rows?

AO12 pseudo-dodecahedron polyhedral volume with K' fitted freely (4.4); sibling row 1153 fixes K' to 4 for the same polyhedron.

V₀
34.77
ų
Polyhedron
K₀
229
GPa
Isothermal
K′
4.400
dimensionless

Volume (V₀)

Value Unit Basis Z
34.77 ų Polyhedron

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
MgO0.88
FeO0.035
Fe2O30.0325
Al2O30.07
SiO20.9

Formula: (Mg0.88Fe3+0.065Fe2+0.035Al0.03)(Al0.11Si0.90)O3

Conditions & method

Tref
Pref
Structure
orthorhombic perovskite (Pbnm/Pnma)
Method
experiment (XRD / DAC / multianvil compression)
single-crystal X-ray diffraction, polyhedral volumes from refined atomic coordinates, up to 64.6(6) GPa
Sample
Fe10-Al14-Bgm, AO12 pseudo-dodecahedron polyhedral volume (K' fitted)

Source

Paper
Single-crystal X-ray diffraction on the structure of (Al,Fe)-bearing bridgmanit…
Authors
Suyu Fu; Stella Chariton; Yanyao Zhang; Takuo Okuchi; Vitali B. Prakapenka; Jung‐Fu Lin
DOI
10.2138/am-2023-8969
Year
2023
Journal
American Mineralogist
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 1: AO12 pseudo-dodecahedron 34.77(7) 229(7) 4.4(2)

Additional notes

volume type
AO12 pseudo-dodecahedron polyhedral volume