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Phase Egg

AlSiO3OH

third-order Birch-Murnaghan · Original · 2018

Why this differs from similar rows?

Refit (in this study) of previously published powder XRD data from Vanpeteghem et al. (2003); sibling row is new single-crystal data collected in this study, a different dataset.

V₀
211.41
ų
Unit cell
K₀
155
GPa
Isothermal
K′
6.700
dimensionless

Volume (V₀)

Value Unit Basis Z
211.41 ų Unit cell

Reported value and unit are preserved as extracted. Z (formula units per cell) is not stored yet, so molar ↔ ų/f.u. conversion is not applied automatically.

Composition

OxideMolar
Al2O30.5
SiO21
H2O0.5

Formula: AlSiO3OH

Conditions & method

Tref
Pref
Structure
other / unspecified
Method
experiment (XRD / DAC / multianvil compression)
refit of published X-ray powder diffraction data (Vanpeteghem et al. 2003) using linearized/Birch-Murnaghan EoS in this study
Sample
powder data of Vanpeteghem et al. (2003), refitted in this study

Source

Paper
High-pressure single-crystal structural analysis of AlSiO3OH phase egg
Authors
Kirsten Schulze; Martha G. Pamato; Alexander Kurnosov; Tiziana Boffa Ballaran; Konstantin Glazyrin; Anna Pakhomova; Hauke Marquardt
DOI
10.2138/am-2018-6562
Year
2018
Journal
American Mineralogist
Origin
Original (measured or fitted in the source paper)

Evidence from the paper

Table 2, 'refitted' column for Vanpeteghem et al. (2003): V0 (Å3) 211.41(11); K0 (GPa) 155(5); K′ 6.7(5). Notes: The axial compressibilities from a previous powder diffraction experiment (Vanpeteghem et al. 2003) have been recalculated in this study.

Additional notes

data source
P-V data from Vanpeteghem et al. (2003); fit performed in this study
axial moduli refitted
{
  "a0": "7.136(6) Å",
  "Ma0": "942(58) GPa",
  "M'a": "12 (second-order Birch-Murnaghan EoS, implied fixed)",
  "b0": "4.322(5) Å",
  "Mb0": "226(21) GPa",
  "M'b": "25(3)",
  "c0": "6.930(5) Å",
  "Mc0": "498(57) GPa",
  "M'c": "32(7)"
}